Journal of the Chemical Society. Chemical communications p. 545 - 546 (1983)
Update date:2022-08-04
Topics:
Bianchini, Claudio
Ghilardi, Carlo A.
Meli, Andrea
Midollini, Stefano
Orlandini, Annabella
The complex <(PPh3)2Cu(η2-BH4)> reacts with CS2 to give the dinuclear copper(I) complex <(PPh3)2Cu(μ-S2CSCH2SCS2)Cu(PPh3)2>; a complete X-ray crystal structure determination has shown that the two (PPh3)2Cu fragments are held together by a bridging S2CSCH2SCS22- ligand, formed from a double head-to-tail condensation of three CS2 molecules.
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