Metal-promoted Trimerization of Carbon Disulphide. Synthesis and Structure of the Dinuclear Copper(I) Complex 3)2Cu(μ-S2CSCH2SCS2)Cu(PPh3)2>

DOI: 10.1039/c39830000545

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 545 - 546 (1983)

Update date:2022-08-04

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Authors:

Bianchini, Claudio

Ghilardi, Carlo A.

Meli, Andrea

Midollini, Stefano

Orlandini, Annabella

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Article abstract of DOI:10.1039/c39830000545

The complex <(PPh3)2Cu(η²-BH4)> reacts with CS2 to give the dinuclear copper(I) complex <(PPh3)2Cu(μ-S2CSCH2SCS2)Cu(PPh3)2>; a complete X-ray crystal structure determination has shown that the two (PPh3)2Cu fragments are held together by a bridging S2CSCH2SCS2^2- ligand, formed from a double head-to-tail condensation of three CS2 molecules.

Full text of DOI:10.1039/c39830000545

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