HYDROXY GROUP-ASSISTED ISOMERIZATION AND ALKYLATION OF ALLYLSILANES IN BASIC MEDIA. α-(1-TRIMETHYLSILYLALLYL) KETONE AS AN α-ALKENYL KETONE EQUIVALENT

DOI: 10.1016/S0040-4039(00)88311-2

Source and publish data:

Tetrahedron Letters p. 4241 - 4244 (1983)

Update date:2022-09-26

Topics:

Authors:

Urabe, Hirokazu

Kuwajima, Isao

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Article abstract of DOI:10.1016/S0040-4039(00)88311-2

Regioselective protonation and alkylation of a certain hydroxyallylsilane have been effected in basic media.An application of these reactions to a facile preparation of 3-hydroxy-1,5-hexadiene systems has also been achieved.

Full text of DOI:10.1016/S0040-4039(00)88311-2

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Product name:Trimethyl-[(1R,2S)-2-((E)-non-1-enyl)-1-vinyl-cyclohexyloxy]-silane

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