
Tetrahedron p. 2691 - 2698 (1983)
Update date:2022-07-29
Topics:
Wada, Masao
Nakai, Hideo
Sato, Yasuhiko
Hatanaka, Yasumaru
Kanaoka, Yuichi
Based on a regioselective remote photocyclization of a pair system consisting of a phthalimide group and dithiolanyl group, a variety of aza-cyclic compounds with methylene, ester, or amide groups in their frameworks were synthesized.The dithiolanyl group provides a removable donor, which effects a needed reaction followed by removal to give a new carbon skeleton leaving little trace of the precursor form.
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