Journal of the Chemical Society. Chemical communications p. 1096 - 1098 (1983)
Update date:2022-07-29
Topics:
Ananthanarayan, T. P.
Magnus, Philip
Norman, Anthony W.
11-Oxygenated steroids with a ring A dienone system are reduced in non-protic media with cleavage of the 9,10-bond, and the resulting 9,10-secosteroids (2) or (5) were converted into 9,10-secocholesta-1,3,5(10)-triene-3-ol (12), an unknown isomer of cholecalciferol (vitamin D3).
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