Tetrahedron p. 3415 - 3418 (1983)
Update date:2022-08-05
Topics:
Hatzigrigoriou, Evagelia
Roux-Schmitt, Marie-Claude
Wartski, Lya
Seyden-Penne, Jacqueline
Merienne, Claude
The stereochemistry of trapping of enolates, resulting from reaction of lithiated arylacetonitriles to cyclenones, by methyl iodide, is examined.In a medium such as THF-HMPT, the trans 2,3-disubstituted cyclanones are obtained with good yields, and moreover in nearly all cases alkylation takes place under kinetic control.
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