Experimental and Theoretical Studies of Dinuclear Gold(I) and Gold(II) Phosphorus Ylide Complexes. Oxidative Addition, Halide Exchange, and Structural Properties Including the Crystal and Molecular Structures of 2 and 2(CH3)Br

DOI: 10.1021/ja00310a028

Source and publish data:

Journal of the American Chemical Society p. 6908 - 6915 (1985)

Update date:2022-08-05

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Authors:

Basil, John D.

Murray, H. H.

Fackler, John P.

Tocher, J. Jr.

Mazany, A. M.

Trzcinska-Bancroft, B. et al.

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Article abstract of DOI:10.1021/ja00310a028

The reactions of the dinuclear phosphorus ylide gold(I) complexes 2, 1, and 2, 2, with the alkyl halides MeI, (Me)3SiCH2I, and PhCH2Br have been studied.It is observed by 1H NMR spectroscopy that equilibrium is rapidly achiev

Full text of DOI:10.1021/ja00310a028

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