211. Michael Addition of Lithio-α-(methyldiphenylsilyl)acetate to Cyclopentenone: A Direct Synthesis of (+/-)-Methyl Jasmonate

DOI: 10.1002/hlca.19830660725

Source and publish data:

Helvetica Chimica Acta p. 2140 - 2144 (1983)

Update date:2022-08-02

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Authors:

Oppolzer, Wolfgang

Guo, Modao

Baetting, Kurt

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Article abstract of DOI:10.1002/hlca.19830660725

Aprotic 1,4-addition of a lithiated α-(methyldiphenylsilyl)acetate to cyclopentenone and in situ enolate alkylation provides a direct synthesis of (+/-)-methyl jasmonate (Scheme 3).

Full text of DOI:10.1002/hlca.19830660725

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