INVESTIGATION OF A CHIRAL MASKED KETENE SYNTHON. SYNTHESIS OF THE (+)-(1R,4R) and (-)-(1S,4S) ENANTIOMERS OF DEHYDRONORCAMPHOR

DOI: 10.1016/S0040-4020(01)91570-4

Source and publish data:

Tetrahedron p. 3245 - 3250 (1983)

Update date:2022-08-04

Topics: Synthesis Enantiomers

Authors:

Maignan, Christian

Raphael, Ralph A.

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Article abstract of DOI:10.1016/S0040-4020(01)91570-4

The Diels-Alder reaction between (+)-(R)-p-tolyl vinyl sulphoxide and cyclopentadiene gives four separable diastereoisomers.The two most abundant were transformed by a two-step procedure into the two enantiomers of dehydronorcamphor (bicyclo<2.2.1>hept-5-

Full text of DOI:10.1016/S0040-4020(01)91570-4

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