HALOGENATION OF UNSATURATED ESTERS-II. ADDITION OF Cl2, BrCl AND Br2 TO METHYL ESTERS OF MONOCHLOROPROPENOIC ACIDS

DOI: 10.1016/S0040-4020(01)91588-1

Source and publish data:

Tetrahedron p. 3367 - 3372 (1983)

Update date:2022-08-03

Topics:

Authors:

Pitkaenen, Maija

Korhonen, Ilpo O. O.

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Article abstract of DOI:10.1016/S0040-4020(01)91588-1

The addition of chlorine, bromine chloride and bromine to methyl 2-chloropropenoate 1, methyl cis-3-chloropropenoate 2 and methyl trans-3-chloropropenoate 3 under ionic and radical conditions gave regioisomer mixtures.Both trans- and cis-addition of halogen species was observed, bromine preferentially adding to the non-halogenated carbon atom.

Full text of DOI:10.1016/S0040-4020(01)91588-1

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