Tetrahedron p. 3367 - 3372 (1983)
Update date:2022-08-03
Topics:
Pitkaenen, Maija
Korhonen, Ilpo O. O.
The addition of chlorine, bromine chloride and bromine to methyl 2-chloropropenoate 1, methyl cis-3-chloropropenoate 2 and methyl trans-3-chloropropenoate 3 under ionic and radical conditions gave regioisomer mixtures.Both trans- and cis-addition of halogen species was observed, bromine preferentially adding to the non-halogenated carbon atom.
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