Syntheses of some methyldiplatinum(I) complexes by oxidative addition or reductive elimination reactions of binuclear complexes

DOI: 10.1021/om00083a009

Source and publish data:

Organometallics p. 697 - 702 (1984)

Update date:2022-08-05

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Authors:

Azam, Kazi A.

Brown, Michael P.

Hill, Ross H.

Puddephatt, Richard J.

Yavari, Ahmad

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Article abstract of DOI:10.1021/om00083a009

Oxidative addition of MeI to [Pt₂(dppm)₃] in benzene followed by anion exchange with K[PF₆] led to isolation of the first methyldiplatinum(I) complex [Pt₂Me(η¹-dppm)(μ-dppm)₂] [PF_{6
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Full text of DOI:10.1021/om00083a009

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Product name:Pt₂(CH₃)2I((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*PF₆^(1-)=(Pt₂(CH₃)2I((C₆H₅)2PCH₂P(C₆H₅)2)2)PF₆

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