Tetrahedron Letters p. 5465 - 5468 (1983)
Update date:2022-08-05
Topics:
Comins, Daniel L.
Brown, Jack D.
Ortho-substituted aryl ketones are prepared from N-<2-(dimethylamino)ethyl>-N-methylbenzamides via ortho lithiation of intermediate α-amino alkoxides, formed in situ by addition of RLi.An ortho lithiation of N-<2-(dimethylamino)ethyl>-N-methylbenzamide is also described.
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