Photosensitized Cycloreversion Reactions of Arylated Cage Compounds in Nonpolar Solvents. Highly Efficient Adiabatic Exciplex Isomerization

DOI: 10.1021/jo00006a039

Source and publish data:

Journal of Organic Chemistry p. 2170 - 2178 (1991)

Update date:2022-08-04

Topics:

Authors:

Hasegawa, Eietsu

Okada, Keiji

Ikeda, Hiroshi

Yamashita, Yoshiro

Mukai, Toshio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00006a039

Photosensitized <2+2> cycloreversion reactions of arylated cage compounds 1 to dienes 2 using several cyanoaromatics as sensitizers are reported.In acetonitrile, 1a isomerized to 2a via an efficient cation-radical chain process.In contrast, the isomerizat

Full text of DOI:10.1021/jo00006a039

Products guided by the article

Product name:C₂₆H₂₈

Cas No:89610-95-7

R&D Labs maybe for 89610-95-7

Changsha Goomoo Chemical Technology Co.Ltd

Contact:+86-731-82197655

Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Shanghai Surseechem Co.,Ltd.

Contact:+86-21-61318535

Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai
Shanghai Goyic Pharmaceutical&Chemical Co,. Ltd

Contact:+86-021-60275964

Address:No. 528 ruiqing road
HANGZHOU YUNUO CHEMICAL CO.,LTD

website:http://www.yunuochem.com

Contact:0571-83715115

Address:hangzhou
Anyang Double Circle Auxiliary CO.,LTD

Contact:0086-134 6082 4403

Address:dongfeng road, anyang city, henan province,china

Relevant to this article

RHODIUM(II) ACETATE-CATALYZED REACTION OF ETHYL 2-DIAZO-3-OXOPENT-4-ENOATES: SIMPLE ROUTES TO 4-ARYL-2-HYDROXY-1-NAPHTHOATES AND β,γ-UNSATURATED ESTERS. THE DIANION OF ETHYL 4-(DIETHYLPHOSPHONO)ACETOACETATE AS A PROPIONATE EQUIVALENT

Doi:10.1016/S0040-4039(00)94110-8
(1983)
THE RELATIVE STEREOCHEMISTRY OF SOME α-METHYL-β-SILYLCARBONYL COMPOUNDS PRODUCED BY THE DIASTEREOSELECTIVE ALKYLATION OF β-SILYLENOLATES

Doi:10.1016/0022-328X(84)85181-5
(1984)
Highly stereocontrolled synthesis of carbacyclin from acyclic starting materials via Ti(II)-Mediated tandem cyclization [10]

Doi:10.1021/ja002974x
(2000)
Doi:10.1021/ja00870a021
(1962)
Redox activation of a B-H bond: A new route to metallaboratrane complexes

Doi:10.1039/b604954k
(2006)
Desymmetrization of meso 7-aza-2,3-bis(phenylsulfonyl) bicyclo[2.2.1]hept-2-ene: a re-examination. Kinetic resolution of racemic 3-arylsulfonyl-7-aza-2-bromobicyclo[2.2.1]hepta-2,5-dienes

Doi:10.1016/j.tetlet.2006.04.014
(2006)

Article Doi