Photosensitized Cycloreversion Reactions of Arylated Cage Compounds in Nonpolar Solvents. Highly Efficient Adiabatic Exciplex Isomerization

DOI: 10.1021/jo00006a039

Source and publish data:

Journal of Organic Chemistry p. 2170 - 2178 (1991)

Update date:2022-08-04

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Authors:

Hasegawa, Eietsu

Okada, Keiji

Ikeda, Hiroshi

Yamashita, Yoshiro

Mukai, Toshio

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Article abstract of DOI:10.1021/jo00006a039

Photosensitized <2+2> cycloreversion reactions of arylated cage compounds 1 to dienes 2 using several cyanoaromatics as sensitizers are reported.In acetonitrile, 1a isomerized to 2a via an efficient cation-radical chain process.In contrast, the isomerizat

Full text of DOI:10.1021/jo00006a039

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