Electrophilic formamidines. Organometallic addition to 2-methoxy pyrrolidine or piperidine N-t-butyl formamidines. Formation of 2-substituted pyrrolidines and piperidines

DOI: 10.1016/S0040-4039(00)97716-5

Source and publish data:

Tetrahedron Letters p. 4723 - 4726 (1990)

Update date:2022-08-04

Topics:

Authors:

Gottlieb

Meyers Meyers

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Article abstract of DOI:10.1016/S0040-4039(00)97716-5

The title compounds were prepared by addition of Grignard reagents to methoxyformamidines 6 and 8 in ether at room temperature. Hydrolysis gives the free secondary amines, or in cases of volatile products, their thiourea derivatives.

Full text of DOI:10.1016/S0040-4039(00)97716-5

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