Photochemical Reactions of Acyclic Monothioimides. A Novel Photorearrangement Involving 1,2-Thiobenzoyl Shift

DOI: 10.1021/jo00184a037

Source and publish data:

Journal of Organic Chemistry p. 1837 - 1838 (1984)

Update date:2022-07-29

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Authors:

Sakamoto, Masami

Aoyama, Hiromu

Omote, Yoshimori

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Article abstract of DOI:10.1021/jo00184a037

Photolysis of N-acylthiobenzamides in benzene gave thioketones via a novel photorearrangement involving 1,2-thiobenzoyl shift; the formation of the products was explainable in terms of β-hydrogen abstraction by the thiocarbonyl group.

Full text of DOI:10.1021/jo00184a037

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