Photochemical Reactions of Acyclic Monothioimides. A Novel Photorearrangement Involving 1,2-Thiobenzoyl Shift

DOI: 10.1021/jo00184a037

Source and publish data:

Journal of Organic Chemistry p. 1837 - 1838 (1984)

Update date:2022-07-29

Topics:

Authors:

Sakamoto, Masami

Aoyama, Hiromu

Omote, Yoshimori

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00184a037

Photolysis of N-acylthiobenzamides in benzene gave thioketones via a novel photorearrangement involving 1,2-thiobenzoyl shift; the formation of the products was explainable in terms of β-hydrogen abstraction by the thiocarbonyl group.

Full text of DOI:10.1021/jo00184a037

Products guided by the article

Product name:Benzamide, N-(phenylthioxomethyl)-N-propyl-

Cas No:89873-90-5

R&D Labs maybe for 89873-90-5

enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Acros Pharmatech Limited

website:http://www.acrospharmatech.com

Contact:+1-3234804688

Address:Flat/RM 1502,Easey Commercial building 253-261 Hennessy Road,Wanchai，HongKong
Cangzhou Senary Chemical Science-tech Co., Ltd

Contact:+86-317-3563899, 3563699

Address:168 Jinde Road, Cangzhou, Hebei, China
Daicel Chiral Technologies (China)CO.,LTD

Contact:021-5046-0086*8

Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
Shanghai SMEC Trading Co., Ltd.

website:http://www.shanghaismec.com

Contact:+86-21-68811293

Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA

Relevant to this article

Synthesis of fused 2′-amino-3′-R-spiro-[indole-3,4′- pyran]-2(1H)-ones

Doi:10.1134/S1070428008120117
(2008)
Stereocontrolled synthesis of the D- and L-glycero-β-D-manno- heptopyranosides and their 6-deoxy analogues. Synthesis of methyl α-L-rhamno-pyranosyl-(1→3)-D-glycero-β-D-manno-heptopyranosyl- (1→3)-6-deoxy-glycero-β-D-manno-heptopyranosyl-(1→4) -α-L-rhamno-pyranoside, a tetrasaccharide subunit of the lipopolysaccharide from Plesimonas shigelloides

Doi:10.1021/ja061594u
(2006)
CATALYTIC AND HYDRIDE REDUCTION OF HEXAFLUOROPROPYLENE DIMERS

Doi:10.1007/BF00954480
(1983)
Synthesis, cytotoxic properties and tubulin polymerization inhibitory activity of novel 2-pyrazoline derivatives

Doi:10.1002/ardp.201100471
(2012)
Synthesis of the First Examples of 1H- and 4H-1,2,4,3λ³-Triazaphospholes via Unexpected Ring-contraction Reactions

Doi:10.1039/c39840000183
(1984)
Enantioselective, intermolecular benzylic C-H amination catalysed by an engineered iron-haem enzyme

Doi:10.1038/nchem.2783
(2017)

Article Doi