Tetrahedron Letters p. 219 - 222 (1984)
Update date:2022-08-05
Topics:
Node, Manabu
Kajimoto, Tetsuya
Nishide, Kiyoharu
Fujita, Eiichi
Fuji, Kaoru
Unsymmetrically substituted 5-membered cyclic ethers were effectively cleaved with the AlCl3-NaI-CH3CN system at the less hindered carbon atom to afford δ-iodoalcohols.Conversion of ent-kaurene to ent-14α- and ent-12β-hydroxykaurene was achieved through t
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