TRIS(PENTAFLUOROPHENYL)PLATINATE(II) COMPLEXES

Article abstract of DOI:10.1016/S0022-328X(00)99190-3

(NBu4)2 reacts with HCl to give (1/1)(NBu4)2 or (1/2)(NBu4)2.Metathetical reactions of the mononuclear PPN salt (PPN/Ph3P=N=PPh3) with KX (X = Br, I, CN or SCN) give complexes of the formula (PPN)2>, whereas reactions with neutral ligands in the presence of a perchlorate MClO4 lead to derivatives of the types Q (L = C2Ph2, dpm or dpe) and Q2<(C6F5)3Pt(L-L)Pt(C6F5)3> (L = dpm or dpe).The reactions of Q with (O3ClO)Pd(C6F5)(PPh3)2, PdCl2(tht)2, PtCl2(tht)2 or AgClO4 give bi- or tri-nuclear derivatives.