Phytochemistry p. 1279 - 1288 (1982)
Update date:2022-08-04
Topics:
Beale, Michael H.
Bearder, John R.
Down, Graham H.
Hutchinson, Michael
MacMillan, Jake
Phinney, Bernard O.
The biosynthesis of 7β-hydroxy- and 7β,18-dihydroxy-kaurenolides from ent-kaur-16-en-19-oic acid has been investigated by incubating unlabelled and labelled putative intermediates with resuspension cultures of Gibberella fujikuroi.The results eliminate pathways which require the loss of oxygen from the 19-oic acid and indicate that the likely pathway is via ent-kaura-6,16-dien-19-oic acid and its ent-6α,7α-epoxide.Key Word Index - Gibberella fujikuroi; resuspension cultures; mutant B1-41a; kaurenoid biosynthesis; 7β-hydroxykaurenolide.
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Doi:10.1021/ja980474m
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