Angewandte Chemie - International Edition p. 4663 - 4666 (2006)
Update date:2022-07-31
Topics:
Kui, Steven C. F.
Huang, Jie-Sheng
Sun, Raymond Wai-Yin
Zhu, Nianyong
Che, Chi-Ming
(Figure Presented) A Moebius arrangement of the bonds directly attached to a metallamacrocycle was observed for the AuI complex [Au 3(CNC)(μ-Ph2PCH2PPh2) 2]+, which was self-assembled by treating the lithium salt of pyridyl-2,6-diphenyl2- (CNC) with [Au2Cl 2(μ-Ph2PCH2PPh2)]. The trinuclear AuI complex has intramolecular Au...Au and C-C...π interactions, exhibits a remarkable stability in solution, and is cytotoxic toward cancer cell lines.
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Doi:10.1021/jo060537g
(2006)Doi:10.1016/j.bmcl.2006.06.030
(2006)Doi:10.1039/c6md00245e
(2016)Doi:10.1021/ol061072j
(2006)Doi:10.1002/anie.202006550
(2020)Doi:10.1021/ol0613766
(2006)
