Stereoselectivity in Intramolecular Amidomercuration. Kinetic vs. Thermodynamic Control

DOI: 10.1021/jo00189a048

Source and publish data:

Journal of Organic Chemistry p. 2838 - 2840 (1984)

Update date:2022-08-03

Topics:

Authors:

Harding, Kenn E.

Marman, Thomas H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00189a048

Stereoselective mercuric ion initiated cyclofunctionalization of δ-alkenylcarbamate 1 requires conditions which do not lead to equilibration , while stereoselective cyclization of the ε-alkenylcarbamate 2 is observed only under conditions which do lead to equilibration .

Full text of DOI:10.1021/jo00189a048

Products guided by the article

Product name:1-Pyrrolidinecarboxylic acid, 2,5-dimethyl-, phenylmethyl ester, cis-

Cas No:91083-67-9

R&D Labs maybe for 91083-67-9

Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
Shantou Baokang Pharmaceutical Co., Ltd.

Contact:+86-754-88873487

Address:5/F B Block Huangshan Bldg Huangshan Rd Shantou
Shenyang Xinyihan Chemical Technology Co., Ltd.

Contact:+86-18525026267

Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China
MENGNA

Contact:18698110882

Address:1303 No2 building,LuoMa Garden,YongAn Road,Hexi District,Tianjin city
Foreschem Co., Ltd

Contact:+86-533-3112891

Address:zibo

Relevant to this article

Synthesis of 2-cyanoacrylamides through Pd-catalyzed monohydration of methylenemalononitriles

Doi:10.1080/00397911.2018.1542496
(2019)
Stereoselective synthesis of 5′-hydroxyzearalenone

Doi:10.1016/j.tetlet.2018.08.030
(2018)
Synthesis of 1-formyldipyrromethanes

Doi:10.1021/jo060119b
(2006)
Doi:10.1021/ja01651a021
(1954)
Vitamin K Dependent Carboxylation: Synthesis and Biological Properties of Tetrazolyl Analogues of Pentapeptidic Substrates

Doi:10.1021/jm00375a027
(1984)
Construction of metal butterflies on a metallacarborane scaffold. 2. Synthesis and structures of hetero-tri- and -tetrametallic clusters

Doi:10.1021/om060418r
(2006)

Article Doi