Stereoselectivity in Intramolecular Amidomercuration. Kinetic vs. Thermodynamic Control

DOI: 10.1021/jo00189a048

Source and publish data:

Journal of Organic Chemistry p. 2838 - 2840 (1984)

Update date:2022-08-03

Topics:

Authors:

Harding, Kenn E.

Marman, Thomas H.

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Article abstract of DOI:10.1021/jo00189a048

Stereoselective mercuric ion initiated cyclofunctionalization of δ-alkenylcarbamate 1 requires conditions which do not lead to equilibration , while stereoselective cyclization of the ε-alkenylcarbamate 2 is observed only under conditions which do lead to equilibration .

Full text of DOI:10.1021/jo00189a048

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