Journal of the Chemical Society. Perkin transactions II p. 409 - 412 (1986)
Update date:2022-08-02
Topics:
Carmona-Guzman, M. Carmen
Balon, Manuel
Gonzalez-Arjona, Domingo
Maraver, Joaquin
Sanchez, Miguel
The kinetics of the reaction between reserpine and potassium peroxodisulphate in acid media have been investigated.The results show two first-order (or pseudo-first-order) steps occuring in series.At the first step, 3-dehydroreserpine, a yellowish green fluorescence product, is obtained, which is afterwards oxidized to 3,5-tetradehydroreserpine, a product with blue fluorescence.These results have been compared with those obtained for other Rauwolfia alkaloids and oxidizing agents.
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