Stereoselective oxy-functionalization of γ-silyl allylic alcohols with ozone: A facile synthesis of silyl peroxide and its reactions

DOI: 10.1021/ol061635r

Source and publish data:

Organic Letters p. 4023 - 4026 (2006)

Update date:2022-07-31

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Authors:

Murakami, Masanori

Sakita, Kyohei

Igawa, Kazunobu

Tomooka, Katsuhiko

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Article abstract of DOI:10.1021/ol061635r

A reaction of γ-silyl allylic alcohol and its ether with ozone provides synthetically versatile α-formyl silyl peroxide in good yield without normal fission of carbon-carbon double bond. Thus, the provided silyl peroxide serves as a good precursor for the

Full text of DOI:10.1021/ol061635r

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