Tetrahedron Letters p. 3239 - 3242 (1985)
Update date:2022-07-30
Topics:
Fujimoto, Yoshinori
Ohhana, Mitsunori
Terasawa, Takeshi
Ikekawa, Nobuo
Petrosterol (1), a cyclopropane-containing C29 marine sterol, has been synthesiyed in a stereocontrolled manner which involves <2,3>-Wittig rearrangement of the propargyl ether (3) yielding the acetylene alcohol (4) with the required C-24, 25 stereochemistry.
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