Journal of Organometallic Chemistry p. 163 - 172 (1985)
Update date:2022-08-03
Topics:
Lukevics, E.
Gevorgyan, V. N.
Goldberg, Y. S.
Shymanska, M. V.
(2-Tetrahydrofuryl)-silanes and -germanes were obtained in high yield by the heterogeneous liquid-phase hydrogenation of <2-(4,5-dihydrofuryl)>trimethylsilane (I), bis<2-(4,5-dihydrofuryl)>dimethylsilane (II) and <2-(4,5-dihydrofuryl)>trimethylgermane with a Pd/Al2O3 catalyst.The dihydrofurylsilanes I and II were found to undergo disproportionation and dehydrogenation, the latter being involved in both intra- and inter-molecular disproportionation.
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