Synthesis of 2,3-disubstituted 1,3-butadienes from organotin precursors and butadienyllithium reagents. Diels-alder reactivity

DOI: 10.1021/ja00068a020

Source and publish data:

Journal of the American Chemical Society p. 6625 - 6635 (1993)

Update date:2022-08-04

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Authors:

Reich, Hans J.

Reich, Ieva L.

Yelm, Kenneth E.

Holladay, Johnathan E.

Gschneidner, David

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Article abstract of DOI:10.1021/ja00068a020

1,4-Bis(trimethylstannyl)-2-butyne (1) and 2,3-bis(trimethylstannyl)-1,3-butadiene (2), versatile synthons for the 2,3-dianion of 1,3-butadiene, have been prepared from either 1,4-dichloro-2-butyne or 2,3-dichloro-1,3-butadiene by reaction with 2 equiv of

Full text of DOI:10.1021/ja00068a020

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