Tetrahedron Letters p. 2209 - 2212 (1984)
Update date:2022-08-03
Topics:
Schnurrenberger, Peter
Hungerbuehler, Ernst
Seebach, Dieter
E-(R)-5-Hydroxy-2-hexenoic acid (4) and the acetonide of E-(4R,5R,7R)-trihydroxy-2-octenoic acid (3) are joined to give, after deprotection, (+)-colletodiol (1).The syntheses of the two hydroxy-acids from poly-(R)-3-hydroxy-butenoate (PHB) and (-)-tartaric acid, respectively, are outlined.
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