Journal of Organometallic Chemistry p. C1 - C4 (1987)
Update date:2022-08-04
Topics:
Brooks, Peter
Craig, Donald C.
Gallagher, Michael J.
Rae, A. David
Sarrof, Adrien
Reaction of alkane-1,n-diylbisdiphenylphosphines with lithium in tetrahydrofuran gives only the diphosphides resulting from cleavage of a phosphorus-aryl bond at each end of the chain; the course of the reaction is independent of chain length.The X-ray structure of the ethane diphosphide is presented and a possible mechanism discussed.
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Doi:10.1016/S0040-4020(01)88447-7
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