THE CLEAVAGE OF P-C BONDS IN DIPHOSPHINES BY LITHIUM: THE CRYSTAL STRUCTURE OF 2(OC4H8)8>

DOI: 10.1016/0022-328X(87)87135-8

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C4 (1987)

Update date:2022-08-04

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Authors:

Brooks, Peter

Craig, Donald C.

Gallagher, Michael J.

Rae, A. David

Sarrof, Adrien

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Article abstract of DOI:10.1016/0022-328X(87)87135-8

Reaction of alkane-1,n-diylbisdiphenylphosphines with lithium in tetrahydrofuran gives only the diphosphides resulting from cleavage of a phosphorus-aryl bond at each end of the chain; the course of the reaction is independent of chain length.The X-ray structure of the ethane diphosphide is presented and a possible mechanism discussed.

Full text of DOI:10.1016/0022-328X(87)87135-8

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