SYNTHESIS OF 1-THIOSUCROSE AND ANOMERS, AND THE BEHAVIOR OF LEVANSUCRASE AND INVERTASE WITH THIS SUBSTRATE ANALOG

Article abstract of DOI:10.1016/0008-6215(84)85287-8

A Lewis acid-catalyzed condensation between 2,3,4,6-tetra-O-acetyl-1-thio-α-D-glucopyranose and 1,3,4,6-tetra-O-benzyl-D-fructofuranose in dichloromethane, followed by a l.c. separation of the deprotected resulting disaccharides, led to 1-thiosucrose (β-D