Tetrahedron p. 2563 - 2568 (1984)
Update date:2022-08-06
Topics:
Barluenga, Jose
Alonso-Cires, Luisa
Campos, Pedro J.
Asensio, Gregorio
The reaction of alkenes with mercury(II) oxide/tetrafluoroboric acid and alcohols or water involves reduction to Hg(O) and vicinal diethers or diols are produced in good yields.Olefins bearing benzylic hydrogens in an α position lead to cinnamyl ethers.Mechanisms are proposed to account for the products and their stereochemistry.
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(1992)
