MERCURY(II) OXIDE/TETRAFLUOROBORIC ACIDPROMOTED VICINAL HYDROXY- AND ALKOXYLATION OF ALKENES

DOI: 10.1016/S0040-4020(01)83510-9

Source and publish data:

Tetrahedron p. 2563 - 2568 (1984)

Update date:2022-08-06

Topics:

Authors:

Barluenga, Jose

Alonso-Cires, Luisa

Campos, Pedro J.

Asensio, Gregorio

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Article abstract of DOI:10.1016/S0040-4020(01)83510-9

The reaction of alkenes with mercury(II) oxide/tetrafluoroboric acid and alcohols or water involves reduction to Hg(O) and vicinal diethers or diols are produced in good yields.Olefins bearing benzylic hydrogens in an α position lead to cinnamyl ethers.Mechanisms are proposed to account for the products and their stereochemistry.

Full text of DOI:10.1016/S0040-4020(01)83510-9

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