MERCURY(II) OXIDE/TETRAFLUOROBORIC ACIDPROMOTED VICINAL HYDROXY- AND ALKOXYLATION OF ALKENES

DOI: 10.1016/S0040-4020(01)83510-9

Source and publish data:

Tetrahedron p. 2563 - 2568 (1984)

Update date:2022-08-06

Topics:

Authors:

Barluenga, Jose

Alonso-Cires, Luisa

Campos, Pedro J.

Asensio, Gregorio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)83510-9

The reaction of alkenes with mercury(II) oxide/tetrafluoroboric acid and alcohols or water involves reduction to Hg(O) and vicinal diethers or diols are produced in good yields.Olefins bearing benzylic hydrogens in an α position lead to cinnamyl ethers.Mechanisms are proposed to account for the products and their stereochemistry.

Full text of DOI:10.1016/S0040-4020(01)83510-9

Products guided by the article

Product name:1H-Indene, 1,2-diethoxy-2,3-dihydro-, trans-

Cas No:93250-33-0

R&D Labs maybe for 93250-33-0

Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
Xi'an Kaixiang Photoelectric Technology Co., Ltd

website:http://www.kxmaterials.com/

Contact:86-29-15991651477

Address:Building 6, Biopharmaceutical Industry R&D Cluster Base, No. 16, Caotang 4th Road, Caotang Science and Technology Industrial Base, High-tech Zone, Xi'an City, Shaanxi Province, China
WD Silicone Co., Ltd

Contact:+86-27-87204219, +86-27-87215023

Address:2402, HuiGu Space-time Building, 8 Forest Road, East Lake Hi-Tech Development Zone
Goldwills Pharmaceuticals Co., Ltd.

Contact:0916-2237889 13991621155

Address:North Suburb of Hanzhong city, Shaanxi Province
Eastar Chemical Corporation

website:http://www.eastarchem.com/

Contact:1-800-898-2436

Address:1215 K Street, STE 1700

Relevant to this article

9-norlignans: Occurrence, properties and their semisynthetic preparation from hydroxymatairesinol

Doi:10.3390/molecules24020220
(2019)
Kinetic Patterns of Condensation of Alkyl- and Cycloalkylcyclopentanones with Dihydric Alcohols in the Presence of Polyoxomolybdate Modified with Oxides of Rare-Earth Elements

Doi:10.1134/S1070427218110204
(2018)
Synthesis of carbazolones and 3-acetylindoles via oxidative C-N bond formation through PIFA-mediated annulation of 2-aryl enaminones

Doi:10.1039/c2ob25348h
(2012)
Preparation of Substituted Tetrahydroisoquinolines by Pd(II)-Catalyzed NH₂-Directed Insertion of Michael Acceptors into C-H Bonds Followed by NH₂-Conjugated Addition

Doi:10.1021/acs.organomet.6b00944
(2017)
Synthesis and structure of a new heterocyclic system - 7,8-dihydroimidazo- [1,2-c][1,3]thiazolo[4,5-e]pyrimidine

Doi:10.1007/s10593-011-0788-y
(2011)
Internal Nucleophilic Termination in Biomimetic Acid Mediated polyene Cyclizations: Stereochemical and Mechanistic Implications. Synthesis of (+/-)-Ambrox and Its Diastereoisomers

Doi:10.1021/jo00029a031
(1992)

Article Doi