CATALYTIC REARRANGEMENT OF α-D-GLUCOSE 1,2-ORTHOACETATE DERIVATIVES OF PREGNENOLONE AND 16-DEHYDROPREGNENOLONE

DOI: 10.1007/BF00579479

Source and publish data:

Chemistry of Natural Compounds p. 177 - 182 (1984)

Update date:2022-09-26

Topics:

Authors:

Samoshina, N. F.

Denisenko, V. A.

Novikov, V. L.

Uvarova, N. I.

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Article abstract of DOI:10.1007/BF00579479

The rearrangement of pregnenolone and 16-dehydropregnenolone α-D-glucose orthoacetates in the presence of mercuric bromide is, because of the high specific selectivity and satisfactory yields of the desired β-D-glucosides, the most effective method of glycosylating the steroids mentioned.

Full text of DOI:10.1007/BF00579479

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