SYNTHESIS OF MANGANESE(I) CARBONYLS WITH ?-BONDED ALKYNYL LIGANDS

DOI: 10.1016/0022-328X(85)80307-7

Source and publish data:

Journal of Organometallic Chemistry p. 379 - 390 (1985)

Update date:2022-08-05

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Authors:

Miguel, D.

Riera, V.

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Article abstract of DOI:10.1016/0022-328X(85)80307-7

A number of ?-alkynylcarbonyl complexes of manganese(I), 5-n(C<*>CR)>, have been obtained from bromocarbonyl complexes 5-nBr> by treatment with silver(I) or copper(I) acetylides, and from perchlorato complexes 5-n(OClO3)> by treatment with 1-alkyne and base.New ?-alkynyl compounds can also be obtained from other alkynyl complexes by reactions involving replacement of CO ligands.

Full text of DOI:10.1016/0022-328X(85)80307-7

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