Journal of Organic Chemistry p. 5225 - 5229 (1988)
Update date:2022-09-26
Topics:
O'Dell, Dale E.
Loper, John T.
Macdonald, Timothy L.
The β-scission of alkoxyl free radicals prepared from thermolysis (77 deg C) of the in situ generated hypoiodite derived from structurally related hydrindan-8-ol and hydrinden-8-ol systems was examined.The course of alkoxyl radical β-scission was sensitive to changes in alkyl substitution at the ring junction site and olefin introduction in the hydrindan skeleton.Thus, the cleavage pattern must reflect the interplay of multiple thermodynamic and kinetic factors.
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