Organometallics p. 199 - 200 (1985)
Update date:2022-07-30
Topics:
Ikariya, Takao
Ho, Suzzy C. H.
Grubbs, Robert H.
The rearrangement of β-phenyltitanacyclobutane (I) to α-phenyltitanacyclobutane (II) is shown through labeling experiments to proceed by a stepwise mechanism. Ring opening of I to the metal-methylidene species followed by readdition of styrene affords both complexes I and II.
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(1952)
