Acceleration of the Reductive Elimination Step in Pd-Catalysed Allylic Alkylation by Allylic Substrates

DOI: 10.1039/c39840000968

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 968 - 969 (1984)

Update date:2022-09-26

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Authors:

Kurosawa, Hideo

Emoto, Mitsuhiro

Urabe, Akira

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Article abstract of DOI:10.1039/c39840000968

Allylic electrophiles used in Pd-catalysed allylic alkylation greatly accelerate reductive elimination of η³-allyl(organo)palladium(II) complexes, via a Pd^IV intermediate, to give the coupling products and η³-allylpalladium(II) salts.

Full text of DOI:10.1039/c39840000968

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