Hexacarbonylmolybdenum(0)-Catalyzed Reaction of Allylic Carbonates with Arylsulfonyl-Stabilized Carbanions

Article abstract of DOI:10.1246/bcsj.60.1525

p-Tolylsulfonylacetonitrile reacted with allylic carbonates in the presence of a catalytic amount of hexacarbonylmolybdenum(0) to give monoallylated derivatives.Using sodium hydride as a base, methyl p-tolylsulfonylacetate reacted with those to give mixtu