Hexacarbonylmolybdenum(0)-Catalyzed Reaction of Allylic Carbonates with Arylsulfonyl-Stabilized Carbanions

DOI: 10.1246/bcsj.60.1525

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1525 - 1526 (1987)

Update date:2022-08-05

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Authors:

Masuyama, Yoshiro

Hirai, Hidenori

Kurusu, Yasuhiko

Segawa, Koh-ichi

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Article abstract of DOI:10.1246/bcsj.60.1525

p-Tolylsulfonylacetonitrile reacted with allylic carbonates in the presence of a catalytic amount of hexacarbonylmolybdenum(0) to give monoallylated derivatives.Using sodium hydride as a base, methyl p-tolylsulfonylacetate reacted with those to give mixtu

Full text of DOI:10.1246/bcsj.60.1525

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