An Improved Synthesis of Triquinacene Derivatives. Two-step Regioselective Oxidation of endo-Dicyclopentadiene to Deslongchamps's Diketone

DOI: 10.1039/c39840000825

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 825 - 826 (1984)

Update date:2022-08-02

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Authors:

Carceller, Elena

Garcia, M. Lluisa

Moyano, Albert

Serratosa, Felix

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Article abstract of DOI:10.1039/c39840000825

endo-Dicyclopentadiene can be regioselectively oxidised, in two steps, to Deslongchamps's diketone (3), from which either 2,3-dihydrotriquinacen-2-one (13) or the corresponding conjugated ketone (14) can be selectively prepared in excellent overall yields.

Full text of DOI:10.1039/c39840000825

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