An Improved Synthesis of Triquinacene Derivatives. Two-step Regioselective Oxidation of endo-Dicyclopentadiene to Deslongchamps's Diketone

DOI: 10.1039/c39840000825

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 825 - 826 (1984)

Update date:2022-08-02

Topics:

Authors:

Carceller, Elena

Garcia, M. Lluisa

Moyano, Albert

Serratosa, Felix

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840000825

endo-Dicyclopentadiene can be regioselectively oxidised, in two steps, to Deslongchamps's diketone (3), from which either 2,3-dihydrotriquinacen-2-one (13) or the corresponding conjugated ketone (14) can be selectively prepared in excellent overall yields.

Full text of DOI:10.1039/c39840000825

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:endo-9-phenylselenotricyclo<5.2.1.0^4,10>dec-5-en-2-one, 2,2-dimethyltrimethylene acetal

Cas No:93832-43-0

R&D Labs maybe for 93832-43-0

shanghai jiuling chemical co.,ltd.

Contact:+86-21-50387295

Address:Zaozhuang Road, Pudong, Shanghai City. China
GUANGZHOU MEDCAN PHARMATECH LTD

website:http://www.gzmedcan.com

Contact:+86-20-82519649

Address:Building J,Room 101,1 JiangtashanRd,Guang Zhou Science City,Guang Zhou ,China
YanCheng LongShen Chemical Co.,Ltd.

Contact:+86-515-86668866

Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
Huzhou City Linghu Xinwang Chemical Co.,Ltd.

Contact:86-572-3948695/3945236

Address:huzhou
Shandong Bolode Bio-Technology Co., LTD

Contact:+86-0531-58966870

Address:136 Jingyi Road,Huaiyin District,Jinan,Shandong,China

Relevant to this article

Intermolecular scandium triflate-promoted nitrene-transfer [5 + 1] cycloadditions of vinylcyclopropanes

Doi:10.1039/c9ob01858a
(2019)
Enantioselective syntheses of both enantiomers of noranabasamine

Doi:10.1021/ol9002288
(2009)
Synthesis of 2-benzothiophene-1(3H)-thione and isothiochromene-1-thione derivatives by iodine-mediated cyclization of lithium 2-(vinyl)dithiobenzoate derivatives

Doi:10.3987/COM-08-11514
(2009)
Dizinc phosphohydrolase model built on a m-terphenyl scaffold and its use in indicator displacement assays for pyrophosphate under physiological conditions

Doi:10.1002/ejoc.200800882
(2009)
Synthesis of some new inolizine and pyrrolo[1,2-a]-quinoline derivatives via nitrogen ylides

Doi:10.3987/COM-08-11527
(2009)
Suppressing unspecific cell uptake for targeted delivery using hydroxyethyl starch nanocapsules

Doi:10.1021/bm300653v
(2012)

Article Doi