STEREOCHEMISTRY IN THE HYDROBORATION OF ALLYLSILANES

DOI: 10.1016/S0040-4039(00)87839-9

Source and publish data:

Tetrahedron Letters p. 2077 - 2080 (1988)

Update date:2022-08-02

Topics:

Authors:

Fleming, Ian

Lawrence, Nicholas, J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)87839-9

The hydroboration of allylsilanes is highly stereoselective in the sense (3 -> 4 and 6->7), especially with 9-BBN as the hydroborating reagent.The products can be converted stereospecifically into 1,3-diol derivatives (5 and 8).

Full text of DOI:10.1016/S0040-4039(00)87839-9

Products guided by the article

Product name:(1RS,2SR)-1-dimethyl(phenyl)silyl-2-methyl-1-phenylpropan-3-ol

Cas No:94286-48-3

R&D Labs maybe for 94286-48-3

Jingzhou TianHe Sci&Tech Chemical Co., Ltd.

Contact:86-716-8331612

Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
ChangZhou Mascotchem. Co.,Ltd.

website:http://www.mascotchem.com

Contact:86-519-85010339

Address:B-802,XingBei Building,391#,Tongjiang Middle Road New District,Changzhou,JS,China
SINO Industries Company Limited(expird)

Contact:86-29-85369724

Address:No.111, Jiefang Road, Xi’an, China
Jiangxi Hessence Chemicals Co., Ltd.

Contact:+86 796 3511924

Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.
Shijiazhuang Sdyano Fine Chemical Co., Ltd

Contact:+86-311-89830448

Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China

Relevant to this article

Crystal and molecular structure analysis of 7-chloro-5-cyclopropyl-9- methyl-10-(2-nitro-4-trifluromethyl-phenyl)-5,10-dihydro-4,5,6, 10-tetraaza-dibenzo [a, d]cyclohepten-11-one

Doi:10.1080/15421400801914970
(2008)
A facile one-pot synthesis of 2-amino-4-arylbenzo[h]quinoline-3- carbonitrile derivatives without catalyst

Doi:10.1002/jhet.5570440337
(2007)
Doi:10.1016/S0039-128X(63)80155-5
(1963)
Studies with enamines: Synthesis and reactivity of 4-nitrophenyl-1- piperidinostyrene. Synthesis of pyridazine, oxadiazole, 1,2,3-triazole and 4-aminopyrazole derivatives

Doi:10.1515/znb-2007-0218
(2007)
A new class of histamine H₃ receptor antagonists derived from ligand based design

Doi:10.1016/j.bmcl.2007.04.056
(2007)
Nonpeptide urotensin-II receptor antagonists: A new ligand class based on piperazino-phthalimide and piperazino-isoindolinone subunits

Doi:10.1021/jm900683d
(2009)

Article Doi