STEREOCHEMISTRY IN THE HYDROBORATION OF ALLYLSILANES

DOI: 10.1016/S0040-4039(00)87839-9

Source and publish data:

Tetrahedron Letters p. 2077 - 2080 (1988)

Update date:2022-08-02

Topics:

Authors:

Fleming, Ian

Lawrence, Nicholas, J.

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Article abstract of DOI:10.1016/S0040-4039(00)87839-9

The hydroboration of allylsilanes is highly stereoselective in the sense (3 -> 4 and 6->7), especially with 9-BBN as the hydroborating reagent.The products can be converted stereospecifically into 1,3-diol derivatives (5 and 8).

Full text of DOI:10.1016/S0040-4039(00)87839-9

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