Tetrahedron Letters p. 3857 - 3860 (1984)
Update date:2022-08-04
Topics:
Honda, Masanori
Katsuki, Tsutomu
Yamaguchi, Masaru
A 16-membered macrolide antibiotic, protomycinolide IV, was synthesized from two fragments to which the chirality was introduced by asymmetric epoxidation of the appropriately chosen allylic alcohols.A new synthesis of the Prelog-Djerassi lactonic acid from one of the intermediates of the synthesis was also carried out.
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Doi:10.1039/c1dt10561b
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