Journal of Organometallic Chemistry p. C11 - C16 (1984)
Update date:2022-08-03
Topics:
Schubert, Ulrich
Hoernig, Hannelore
When solid (CO)5CrC(OEt)SiPh3 is thermolysed, two different reaction pathways are observed: (i) fragmentation to give Cr(CO)6, triphenylsilane and ethylene; and (ii) cleavage of the bond between the chromium atom and the carbene carbon to yield both ethyl(triphenylsilyl)ketone (3) and a metal complex, in which one of the phenyl groups of 3 is ?-bonded to a Cr(CO)3 moiety.If thermolysis is carried out in dioxane solution, the ketone portion increases considerably.However, in pyridine solution ethoxytriphenylsilane and hexaphenyldisiloxane are formed.
Contact:+86-571-86217390
Address:No.567 Dengcai Street,Sandun,Westlake District,Hangzhou310030,Zhejiang,China.
Contact:+86-574- 87178138; 87297407
Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
Shifang Taifeng New Flame Retardant Co., Ltd
Contact:02884721008
Address:tingjiang industrial park, hefeng town
Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.
Contact:+86-750-2881198
Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
Contact:+86-25-52346955
Address:199,JIANYE ROAD,NANJING,CHINA
Doi:10.1016/j.tet.2007.01.072
(2007)Doi:10.1016/S0040-4039(01)01883-4
(2001)Doi:10.1021/jo00204a022
(1985)Doi:10.1002/anie.200603347
(2007)Doi:10.1016/0022-328X(87)85007-6
(1987)Doi:10.1002/ejoc.201301366
(2013)
