Organic Letters p. 2560 - 2563 (2007)
Update date:2022-08-04
Topics: Optically pure Asymmetric reduction Enzymatic transformation Workup and Isolation Reaction Conditions Enzyme Selection Substrate Selection Analysis Chiral Control
Zhu, Dunming
Ankati, Haribabu
Mukherjee, Chandrani
Yang, Van
Biehl, Edward R.
Hua, Ling
α-Ethylation is concomitant with the reduction of aromatic β-ketonitriles catalyzed by whole-cell biocatalysts. Use of isolated carbonyl reductase has completely eliminated this competing reaction. (R)-β-Hydroxy nitriles were obtained via a reduction cata
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