Journal of the American Chemical Society p. 7744 - 7745 (2007)
Update date:2022-07-29
Topics:
Su, Shun
Porco Jr., John A.
Synthesis of pyrrolo-isoquinolines related to the lamellarin alkaloids employing silver-catalyzed cycloisomerization-dipolar cycloaddition of alkynyl N-benzylidene glycinates is described. Mechanistic studies revealed Ag(I)-catalyzed cycloisomerization to an azomethine ylide as a key step for formation of angular pyrrolo-isoquinolines. Copyright
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