Synthetic Approach to the Amphilectane Diterpenes: The Use of Nitriles as Terminators of Carbocation-Olefin Cyclizations

DOI: 10.1021/jo00205a015

Source and publish data:

Journal of Organic Chemistry p. 632 - 640 (1985)

Update date:2022-08-03

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Authors:

Stevens, Robert V.

Albizati, Kim F.

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Article abstract of DOI:10.1021/jo00205a015

A biomimetic approach to the synthesis of tricyclic terpenoid isonitriles from marine sponges is described which involves carbocation-olefin cyclization of polyolefinic precursors terminated by the stereoselective formation of a carbon-nitrogen bond.The k

Full text of DOI:10.1021/jo00205a015

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