Stereoselective Synthesis of Quaternary Carbon Atoms

DOI: 10.1039/c39840000747

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 747 - 748 (1984)

Update date:2022-07-29

Topics:

Authors:

Curtis, Penelope J.

Davies, Stephen G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840000747

Repeated deprotonation and alkylation of <(η⁵-C5H5)Fe(PPh3)(CO)(=cyclo)>+ allows the stereoselective synthesis of quaternary carbon centres to be achieved with decomplexation leading to 2,2-dialkylbutyrolactones.

Full text of DOI:10.1039/c39840000747

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(C₅H₅)Fe(CO)(P(C₆H₅)3)(CCHCH₂CH₂O)

Cas No:94792-64-0

R&D Labs maybe for 94792-64-0

APOLLO HEALTHCARE RESOURCES

Contact:+65 9658 0999

Address:26 Sin Ming Lane, Midview City, #05-118, Singapore 573971
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing
Linyi VIHO Chemical Co.,Ltd

Contact:86-15588110016

Address:LINYI CITY,SHANDONG PROVINCE,CHINA
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China

Relevant to this article

Volatile methyl esters of medium chain length from the bacterium Chitinophaga Fx7914

Doi:10.1002/cbdv.201000190
(2010)
NHCs-mediated benzoates formation directly from aromatic aldehydes and alkyl halides

Doi:10.1016/j.tet.2012.02.079
(2012)
Reactions of 5,6-Dilithioacenaphthene-N,N,N',N'-Tetramethyl-1,2-ethanediamine Complex with α-Diketones. II. Competitive Oxophilic and Carbophilic Additions and Redox Reactions

Doi:10.1246/bcsj.54.3026
(1981)
The first isocyanide of plant origin expands functional group diversity in cruciferous phytoalexins: Synthesis, structure and bioactivity of isocyalexin A

Doi:10.1039/c2ob25492a
(2012)
Direct α-oxytosylation of ketones by using pentavalent organobismuth reagents

Doi:10.1246/cl.2008.388
(2008)
Further enolate alkylation studies of 2,5-dimethyl-3(2H)-furanone

Doi:10.1055/s-2004-831300
(2004)

Article Doi