Stereoselective Synthesis of Quaternary Carbon Atoms

DOI: 10.1039/c39840000747

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 747 - 748 (1984)

Update date:2022-07-29

Topics:

Authors:

Curtis, Penelope J.

Davies, Stephen G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840000747

Repeated deprotonation and alkylation of <(η⁵-C5H5)Fe(PPh3)(CO)(=cyclo)>+ allows the stereoselective synthesis of quaternary carbon centres to be achieved with decomplexation leading to 2,2-dialkylbutyrolactones.

Full text of DOI:10.1039/c39840000747

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(C₅H₅)Fe(CO)(P(C₆H₅)3)(CCHCH₂CH₂O)

Cas No:94792-64-0

R&D Labs maybe for 94792-64-0

Hangzhou Yingshanhua Pigment Chemicals Co.,Ltd.

Contact:+86-0150-58101658

Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China
Chongqing Changfeng Chemical Co., Ltd.

website:http://www.changfengchem.com

Contact:+86-23-67896333

Address:30th Floor, Longhu Ziduxingzuo Building A, 1st Branch,YuSong Rd., Yubei District, Chongqing, China
Nantong Auxin Electronic Technology Co., LTD

Contact:86-513-88760026

Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
JIAXING SUNS INTERNATIONAL TRADE CO LTD

Contact:18367306858

Address:No.123,Huixin Avenue,Huimin Dist
Brichem ( Haikou ) Co. Ltd.

Contact:86-898-65311214

Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China

Relevant to this article

Volatile methyl esters of medium chain length from the bacterium Chitinophaga Fx7914

Doi:10.1002/cbdv.201000190
(2010)
NHCs-mediated benzoates formation directly from aromatic aldehydes and alkyl halides

Doi:10.1016/j.tet.2012.02.079
(2012)
Reactions of 5,6-Dilithioacenaphthene-N,N,N',N'-Tetramethyl-1,2-ethanediamine Complex with α-Diketones. II. Competitive Oxophilic and Carbophilic Additions and Redox Reactions

Doi:10.1246/bcsj.54.3026
(1981)
The first isocyanide of plant origin expands functional group diversity in cruciferous phytoalexins: Synthesis, structure and bioactivity of isocyalexin A

Doi:10.1039/c2ob25492a
(2012)
Direct α-oxytosylation of ketones by using pentavalent organobismuth reagents

Doi:10.1246/cl.2008.388
(2008)
Further enolate alkylation studies of 2,5-dimethyl-3(2H)-furanone

Doi:10.1055/s-2004-831300
(2004)

Article Doi

Stereoselective Synthesis of Quaternary Carbon Atoms

DOI: 10.1039/c39840000747

Source and publish data:

Authors:

Article abstract of DOI:10.1039/c39840000747

Full text of DOI:10.1039/c39840000747

Products guided by the article

R&D Labs maybe for 94792-64-0

Relevant to this article

Volatile methyl esters of medium chain length from the bacterium Chitinophaga Fx7914

NHCs-mediated benzoates formation directly from aromatic aldehydes and alkyl halides

Reactions of 5,6-Dilithioacenaphthene-N,N,N',N'-Tetramethyl-1,2-ethanediamine Complex with α-Diketones. II. Competitive Oxophilic and Carbophilic Additions and Redox Reactions

The first isocyanide of plant origin expands functional group diversity in cruciferous phytoalexins: Synthesis, structure and bioactivity of isocyalexin A

Direct α-oxytosylation of ketones by using pentavalent organobismuth reagents

Further enolate alkylation studies of 2,5-dimethyl-3(2H)-furanone