Stereoselective Synthesis of Quaternary Carbon Atoms

DOI: 10.1039/c39840000747

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 747 - 748 (1984)

Update date:2022-07-29

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Authors:

Curtis, Penelope J.

Davies, Stephen G.

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Article abstract of DOI:10.1039/c39840000747

Repeated deprotonation and alkylation of <(η⁵-C5H5)Fe(PPh3)(CO)(=cyclo)>+ allows the stereoselective synthesis of quaternary carbon centres to be achieved with decomplexation leading to 2,2-dialkylbutyrolactones.

Full text of DOI:10.1039/c39840000747

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Product name:(C₅H₅)Fe(CO)(P(C₆H₅)3)(CCHCH₂CH₂O)

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