CO assistance in ligand exchange of a ruthenium racemization catalyst: Identification of an acyl intermediate

DOI: 10.1021/ja9038455

Source and publish data:

Journal of the American Chemical Society p. 9500 - 9501 (2009)

Update date:2022-08-05

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Authors:

Aberg, Jenny B.

Nyhlen, Jonas

Martin-Matute, Belen

Privalov, Timofei

Baeckvall, Jan-E.

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Article abstract of DOI:10.1021/ja9038455

(Chemical Equation Presented) An acyl intermediate in the activation of η⁵-(Ph₅Cp)Ru(CO)₂Cl by t-BuOK was identified by means of in situ FT-IR measurements and NMR spectroscopy. This strongly supports the conclusion that t

Full text of DOI:10.1021/ja9038455

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