Journal of the Chemical Society. Perkin transactions I p. 2779 - 2783 (1984)
Update date:2022-08-03
Topics:
Hunter, Daniel
Neilson, Douglas G.
s-Tetrazines having aryl substituents in either the 3- or 3,6-positions react readily with alkyl or aryl Grignard reagents to give 1-alkyl(or aryl)-1,4-dihydro-s-terazines.The 1-alkyl-1,4-dihydro-s-tetrazines rearrange in methanolic hydrogen chloride to 4-alkylamino-1,2,4-triazoles, but thermolyse readily to the less well known, isomeric 1-alkylamino-1,2,4-triazoles.Possible reaction pathways involving breakdown to nitrile and reactive intermediates such as 1,3-dipolar species are discussed.
View MoreHebei Think-Do Environment Co., Ltd
website:http://www.thinkdo-environment.com
Contact:0311-86510809
Address:No 6, Shilian Middle Street, Circular Chemical Industry Park
Contact:0086-29-88315623
Address:S711, Innovation Bldg No.25 Gaoxin 1st Rd, Xian P.R of China 710075
qingcang(shanghai) Medical Technology Co., Ltd.
Contact:021-58099007
Address:shanghai
Zibo Ocean International Trade Co.,Ltd(expird)
Contact:+86 533 5160706
Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)
Contact:+86-512-69598882
Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
Doi:10.1002/recl.19831021207
(1983)Doi:10.1039/c8sc01410h
(2018)Doi:10.1016/j.tetlet.2008.09.045
(2008)Doi:10.1021/jo00183a027
(1984)Doi:10.1016/S0040-4039(01)99805-3
(1983)Doi:10.1016/j.bmcl.2018.05.035
(2018)