N-(TRIMETHYLSILYLMETHYL)CARBODIIMIDES AND -KETENIMINE AS PRECURSORS OF IMINO- AND ALKYLIDENE-2-AZAALLYL ANIONS

DOI: 10.1246/cl.1984.1827

Source and publish data:

Chemistry Letters p. 1827 - 1830 (1984)

Update date:2022-07-30

Topics:

Authors:

Tsuge, Otohiko

Kanemasa, Shuji

Matsuda, Koyo

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Article abstract of DOI:10.1246/cl.1984.1827

The fluoride-induced desilylation of N-(trimethylsilylmethyl)carbodiimides and -ketenimine generates imino- and alkylidene-2-azaallyl anions which cycloadd to a variety of aldehydes giving regioisomeric 1,3-oxazolidines as cycloadducts.

Full text of DOI:10.1246/cl.1984.1827

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