Chemical and Pharmaceutical Bulletin p. 3525 - 3531 (1984)
Update date:2022-09-26
Topics:
Ohshima
Sai
Takatsuto
Ikekawa
Kobayashi
Tanaka
DeLuca
trans Diaxial opening with potassium hydrogen difluoride of the 1β,2β-epoxy-3β-ol derived from cholenic acid gave the 1α-fluoro-2β,3β-diol derivative. Construction of the 25-hydroxy cholesterol side chain and deoxygenation of the 2β-hydroxy group afforded
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