STEREOSELECTIVE SYNTHESIS OF (1R,3S)-CIS-CHRYSANTHEMIC ACID THROUGH MICROBIOLOGICAL REDUCTION OF 2,2,5,5-TETRAMETHYL 1,4-CYCLOHEXANEDIONE.

DOI: 10.1016/S0040-4039(01)81744-5

Source and publish data:

Tetrahedron Letters p. 6005 - 6006 (1984)

Update date:2022-08-03

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Authors:

Buisson, Didier

Azerad, Robert

Revial, Gilbert

d'Angelo, Jean

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Article abstract of DOI:10.1016/S0040-4039(01)81744-5

An efficient, highly stereoselective synthesis of (1R,3S)-cis-chrysanthemic acid 6 is described.The crucial step of this synthesis was the microbiological reduction of dione 1 into (S)-ketol 2.

Full text of DOI:10.1016/S0040-4039(01)81744-5

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