NEW NEUTRAL AND CATIONIC DICYCLOPENTADIENYLNIOBIUM COMPLEXES

DOI: 10.1016/0022-328X(84)80630-0

Source and publish data:

Journal of Organometallic Chemistry p. 185 - 192 (1984)

Update date:2022-07-31

Topics:

Authors:

Urbanos, F.A.

Mena, M.

Royo, P.

Antinolo, A.

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Article abstract of DOI:10.1016/0022-328X(84)80630-0

(η⁵-C5H5)2NbX(PMe3) (X = Cl, Br) was prepared by reducing (η⁵-C5H5)2NbX2 with Na/Hg amalgam in the presence of PMe3. (η⁵-C5H4Me)2TaCl(PMe3) was obtained analogously.The reaction of (η⁵-C5H5)2NbCl(PMe3) with AgBF

Full text of DOI:10.1016/0022-328X(84)80630-0

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Product name:[(η5-C5H5)2Nb(PMe3)(OPPh3)](BF4)Cl

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