An Extremely Facile Ring Opening of Substituted 1-(Alkylthio)cyclopropenes via Vinylcarbene Intermediates

DOI: 10.1021/jo00207a055

Source and publish data:

Journal of Organic Chemistry p. 1145 - 1147 (1985)

Update date:2022-08-05

Topics:

Authors:

Yoshida, Hiroshi

Kato, Makoto

Ogata, Tsuyoshi

Matsumoto, Kiyoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00207a055

Thermal ring opening of 1-(methylthio)cyclopropenes 2 takes place readily to give indene and/or butadiene derivatives in good yields, and product analysis of the reaction in methanol as well as kinetic studies of 2b gave strong evidence for the intermedia

Full text of DOI:10.1021/jo00207a055

Products guided by the article

Product name:Benzene, 1,1'-[3-methyl-3-(methylthio)-1-cyclopropene-1,2-diyl]bis-

Cas No:95616-11-8

R&D Labs maybe for 95616-11-8

Nanjing Legend Pharmaceutical & Chemical Co., Ltd.

Contact:+86-25-83767696

Address:14-7 Zhongshan Lu Guluo District, Nanjing
Shandong General Materials Co.,Ltd（Shandong Aoertong Chemical Co., Ltd）

Contact:86-531-88072280

Address:No. 1825 Hualong Road, Licheng District, Jinan, Shandong, China
Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China
Shanghai chemrole co.,ltd

Contact:021-50278900

Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china
Yixing Bluwat Chemicals Co., Ltd.

Contact:+86 510 87821568

Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China

Relevant to this article

Photoreaction of (RS,SR)-3-phenyl-6-hepten-2-ol. Benzene-olefin cycloadditions as a synthetic route to [5.5.5.5]fenestranes. Part III

Doi:10.1002/hlca.19840670731
(1984)
Novel preparation of functionalized iodotetrahydronaphthyridine, iodoazaindoline, and iodotetrahydropyridoazepine systems

Doi:10.1016/j.tetlet.2007.08.076
(2007)
Organocatalytic enantioselective protonation of silyl enolates mediated by cinchona alkaloids and a latent source of HF

Doi:10.1002/anie.200701683
(2007)
A synthesis of DL-tryptophan from acrolein.

Doi:10.1246/bcsj.41.2975
(1968)
Electronic and optical properties of ladder-type heteraborins

Doi:10.1002/chem.200700622
(2007)
Total synthesis of the 5-epimers of naturally occurring (-)-hyacinthacine A₅ and unnatural (+)-hyacinthacine A₄

Doi:10.1016/j.tetasy.2007.09.014
(2007)

Article Doi