An Extremely Facile Ring Opening of Substituted 1-(Alkylthio)cyclopropenes via Vinylcarbene Intermediates

DOI: 10.1021/jo00207a055

Source and publish data:

Journal of Organic Chemistry p. 1145 - 1147 (1985)

Update date:2022-08-05

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Authors:

Yoshida, Hiroshi

Kato, Makoto

Ogata, Tsuyoshi

Matsumoto, Kiyoshi

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Article abstract of DOI:10.1021/jo00207a055

Thermal ring opening of 1-(methylthio)cyclopropenes 2 takes place readily to give indene and/or butadiene derivatives in good yields, and product analysis of the reaction in methanol as well as kinetic studies of 2b gave strong evidence for the intermedia

Full text of DOI:10.1021/jo00207a055

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Product name:Benzene, 1,1'-[3-methyl-3-(methylthio)-1-cyclopropene-1,2-diyl]bis-

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