Tetrahedron Letters p. 5929 - 5932 (1984)
Update date:2022-08-02
Topics:
Moiseenkov, A. M.
Veselovsky, V. V.
Makarova, Z. G.
Zhulin, V. M.
Smit, W. A.
Lewis acid initiated reaction of isoprene with PhSOCl proceeds in a ene fashion with the formation of 2-phenylsulfinylmethyl-1,3-butadiene.High pressure promoted addition produces Z-1-phenylsulfinyl-4-chloroadduct presumably via <4+2> cycloaddition.
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